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• W2055177367 abstract "D–π–A and D–A–π–A-structured organic dyes represent different developmental directions of photosensitizers in dye-sensitized solar cells (DSSCs). In this work, two phenothiazine derivatives-based D–π–A and D–A–π–A-structured organic dyes have been synthesized and applied in DSSCs. The physical and electrochemical properties of both dyes have been investigated systematically. The results show that the D–A–π–A-structured dye exhibits a broader spectrum response but lower molar coefficient of extinction when compared to the D–π–A-structured dye. Regarding photovoltaic performance, the D–π–A-structured dye yields a higher efficiency (η) of 7.5% with a higher short-circuit current density (Jsc) of 16.36 mA cm−2 and open-circuit voltage (Voc) of 706 mV than that of the D–A–π–A-structured dye. Incident photon-to-electron conversion efficiency (IPCE) studies and impedance analysis also support these results. These results demonstrate that the phenothiazine derivatives-based D–π–A-structured organic dyes can compete with, and even exceed, D–A–π–A-structured organic dyes under the same test conditions." @default.
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• W2055177367 date "2014-01-01" @default.
• W2055177367 modified "2023-10-04" @default.
• W2055177367 title "Phenothiazine derivatives-based D–π–A and D–A–π–A organic dyes for dye-sensitized solar cells" @default.
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• W2055177367 doi "https://doi.org/10.1039/c4ra01858c" @default.
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