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- W2055185710 abstract "Abstract Exchange of halide (or pseudohalide) was found to occur in reactions between [(PPh2R)2Pd(CH2SR′)X] (R = Me or Ph; R′ = Me or Ph; X = Cl, Br or SCN) and alkyl halides (Mel, Etl or EtBr) in chloroform solution at room temperature. The reactivity of the alkyl halides was in the sequence Mel > Etl > EtBr. There was no evidence for PdC bond cleavage. Complexes containing the bidentate CH2SMe group, e.g. [(PPh3)Pd(CH2SMe)X] (X = Cl, Br or I), undergo exchanges with alkyl halides much more slowly." @default.
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- W2055185710 date "1984-01-01" @default.
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- W2055185710 title "Sulphur substituted alkylpalladium compounds. Part 3. Reactions of organothionemethyl-palladium compounds with alkyl halides" @default.
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- W2055185710 doi "https://doi.org/10.1016/s0020-1693(00)88732-0" @default.
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