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- W2055201725 abstract "The orthorhombic — tetragonal phase transition of YBa2Cu3O6+δ has been investigated by X-ray powder diffraction methods. The transition is of the second order or very close to second order and no coexistence of tetragonal and orthorhombic phases has been observed. The transition strongly depends on the oxygen index δ which changes with temperature. Typical patterns of the triplet 006, 020, and 002 obtained by precise X-ray powder diffraction measurements have been presented and shown to be useful for identification of YBa2Cu3O6+δ and estimation of oxygen index δ. Ein orthorhombisch-tetragonaler Phasenübergang in YBa2Cu3O6+δ wurde mit Hilfe eines Röntgen-Pulverdiffraktometers untersucht. Der Übergang ist zweiter Art. Es wurde keine Koexistenz der tetragonalen und orthorhombischen Phasen beobachtet. Der Übergang ist stark vom Sauerstoffindex abhängig und ändert sich mit der Temperatur. Die typischen Linien des 006, 020, und 002 Triplets, die mit Hilfe von Pulverdiagrammen erhalten wurden, sind ausschlaggebend für die Identifizierung des YBa2Cu3O6+δ und des Sauerstoffindex." @default.
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- W2055201725 date "1988-03-01" @default.
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- W2055201725 title "Orthorhombic — tetragonal phase transition and oxygen index of YBa2Cu3O6+δ" @default.
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- W2055201725 doi "https://doi.org/10.1002/crat.2170230312" @default.
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