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- W2055285545 abstract "A combined experimental and computational investigation has shown that the photocyclization of 2-azadienes to isoquinolines is consistent with a unimolecular process in the triplet state and that the (n,π*) transition is involved. The presence of a methoxy group favours the photoreaction. According to calculations, the reaction should proceed by a conformational equilibrium in the ground state followed by excitation and subsequent cyclization. The presence of an equilibrated triplet-state intermediate along the reaction path is consistent with a measurable luminescence." @default.
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- W2055285545 date "2013-09-01" @default.
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- W2055285545 title "Role of the electron-donating methoxy group on the photo-induced cyclization of 2-azadienes: a mechanistic study" @default.
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- W2055285545 doi "https://doi.org/10.1016/j.tet.2013.07.015" @default.
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