Matches in SemOpenAlex for { <https://semopenalex.org/work/W2055291270> ?p ?o ?g. }
- W2055291270 endingPage "91" @default.
- W2055291270 startingPage "81" @default.
- W2055291270 abstract "Stimuli-responsive spherical brushes composed of 6-O-methacryloyl-1,2:3,4-di-O-isopropylidene-D-galactopyranose (MAIGal) and 2-(dimethylamino)ethyl methacrylate (DMAEMA) are prepared via atom transfer radical polymerization (ATRP) using cross-linked polystyrene nanoparticles covered with a thin layer of 2-(2-bromoisobutyryloxy)ethyl methacrylate (BIEM) as ATRP initiator by the “grafting from” approach. The stimuli-responsive behavior of the deprotected spherical PMAGal-b-PDMAEMA block copolymer brushes is investigated by dynamic light scattering and cryogenic transmission electron microscopy. A brush with arms containing 160 MAGal and 170 DMAEMA monomer units shows a significant contraction of the hydrodynamic radius from 20 to 70 °C at pH = 8 with a cloud point at ≈40 °C, whereas no LCST is detected at pH = 6 and 7 due to the protonation of the DMAEMA units. Aggregates occur at low temperatures and pH 8 due to intermolecular interactions between the chains of different brushes, which disappear above LCST, when the PDMAEMA chains fold back to the core of the brushes, exposing the glycopolymer chains to the outside." @default.
- W2055291270 created "2016-06-24" @default.
- W2055291270 creator A5035278528 @default.
- W2055291270 creator A5056032704 @default.
- W2055291270 creator A5068187068 @default.
- W2055291270 creator A5073420023 @default.
- W2055291270 creator A5083890674 @default.
- W2055291270 date "2013-09-17" @default.
- W2055291270 modified "2023-10-02" @default.
- W2055291270 title "Stimuli-Responsive Spherical Brushes Based on D -Galactopyranose and 2-(Dimethylamino)ethyl Methacrylate" @default.
- W2055291270 cites W1965676449 @default.
- W2055291270 cites W1967812778 @default.
- W2055291270 cites W1968954284 @default.
- W2055291270 cites W1969786495 @default.
- W2055291270 cites W1970025394 @default.
- W2055291270 cites W1974499808 @default.
- W2055291270 cites W1974571564 @default.
- W2055291270 cites W1974772173 @default.
- W2055291270 cites W1981037158 @default.
- W2055291270 cites W1988155694 @default.
- W2055291270 cites W1991789763 @default.
- W2055291270 cites W1993308132 @default.
- W2055291270 cites W1995992975 @default.
- W2055291270 cites W1996760020 @default.
- W2055291270 cites W1997104740 @default.
- W2055291270 cites W2006214486 @default.
- W2055291270 cites W2011553688 @default.
- W2055291270 cites W2013596690 @default.
- W2055291270 cites W2014263599 @default.
- W2055291270 cites W2015149981 @default.
- W2055291270 cites W2015593851 @default.
- W2055291270 cites W2016548996 @default.
- W2055291270 cites W2020027505 @default.
- W2055291270 cites W2022743550 @default.
- W2055291270 cites W2026138397 @default.
- W2055291270 cites W2036663644 @default.
- W2055291270 cites W2037280109 @default.
- W2055291270 cites W2037864161 @default.
- W2055291270 cites W2039289241 @default.
- W2055291270 cites W2040101471 @default.
- W2055291270 cites W2043586030 @default.
- W2055291270 cites W2044300232 @default.
- W2055291270 cites W2046884231 @default.
- W2055291270 cites W2047048874 @default.
- W2055291270 cites W2050407603 @default.
- W2055291270 cites W2051678562 @default.
- W2055291270 cites W2052645986 @default.
- W2055291270 cites W2055910769 @default.
- W2055291270 cites W2069197845 @default.
- W2055291270 cites W2070128508 @default.
- W2055291270 cites W2073201602 @default.
- W2055291270 cites W2073556065 @default.
- W2055291270 cites W2090226885 @default.
- W2055291270 cites W2093160532 @default.
- W2055291270 cites W2097861635 @default.
- W2055291270 cites W2098908854 @default.
- W2055291270 cites W2109512179 @default.
- W2055291270 cites W2114152398 @default.
- W2055291270 cites W2115261745 @default.
- W2055291270 cites W2124961089 @default.
- W2055291270 cites W2136227935 @default.
- W2055291270 cites W2167829123 @default.
- W2055291270 cites W2170347782 @default.
- W2055291270 cites W2328065657 @default.
- W2055291270 doi "https://doi.org/10.1002/mabi.201300290" @default.
- W2055291270 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24106068" @default.
- W2055291270 hasPublicationYear "2013" @default.
- W2055291270 type Work @default.
- W2055291270 sameAs 2055291270 @default.
- W2055291270 citedByCount "20" @default.
- W2055291270 countsByYear W20552912702014 @default.
- W2055291270 countsByYear W20552912702015 @default.
- W2055291270 countsByYear W20552912702016 @default.
- W2055291270 countsByYear W20552912702017 @default.
- W2055291270 countsByYear W20552912702018 @default.
- W2055291270 countsByYear W20552912702019 @default.
- W2055291270 countsByYear W20552912702020 @default.
- W2055291270 countsByYear W20552912702021 @default.
- W2055291270 countsByYear W20552912702022 @default.
- W2055291270 crossrefType "journal-article" @default.
- W2055291270 hasAuthorship W2055291270A5035278528 @default.
- W2055291270 hasAuthorship W2055291270A5056032704 @default.
- W2055291270 hasAuthorship W2055291270A5068187068 @default.
- W2055291270 hasAuthorship W2055291270A5073420023 @default.
- W2055291270 hasAuthorship W2055291270A5083890674 @default.
- W2055291270 hasConcept C132050475 @default.
- W2055291270 hasConcept C14631669 @default.
- W2055291270 hasConcept C150539798 @default.
- W2055291270 hasConcept C155672457 @default.
- W2055291270 hasConcept C15920480 @default.
- W2055291270 hasConcept C166940927 @default.
- W2055291270 hasConcept C171250308 @default.
- W2055291270 hasConcept C178790620 @default.
- W2055291270 hasConcept C185592680 @default.
- W2055291270 hasConcept C188027245 @default.
- W2055291270 hasConcept C188109995 @default.
- W2055291270 hasConcept C192562407 @default.
- W2055291270 hasConcept C207374878 @default.