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- W2055292893 abstract "The effects of the addition of cerium or Ce-rich mischmetal (Mm) on the electrochemical characteristics of the ZrNi1.1Mn0.5V0.3Cr0.1 hydrogen storage alloy electrodes were investigated. The results showed that a small addition of Ce or Mm improve greatly the activation behavior of ZrNi1.1Mn0.5V0.3Cr0.1 alloy electrodes. It was found that Zr0.9M0.1Ni1.1Mn0.5V0.3Cr0.1 (M=Ce, Mm) alloy electrodes can be activated before 3∼4 charge/discharge cycles in comparison with about 27 cycles needed to activate ZrNi1.1Mn0.5V0.3Cr0.1 alloy electrode. In addition, the maximum discharge capacity was increased from 300 mAh/g to 316∼340 mAh/g owing to the addition of Ce or Mm. However, the addition of Ce or Mm has a negative effect on the cyclic durability of Zr-based alloy electrodes. The dispersive CeNi or MmNi phases in the parent alloy act as active sites for hydrogen electrode reaction to improve markedly the electrocatalytic activity of the Zr-based alloy electrodes. Therefore, the Zr0.9M0.1Ni1.1Mn0.5V0.3Cr0.1 alloy electrodes exhibited higher exchange current density and lower apparent activation energy for the hydrogen electrode reaction than ZrNi1.1Mn0.5V0.3Cr0.1 alloy electrode." @default.
- W2055292893 created "2016-06-24" @default.
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- W2055292893 date "2001-04-01" @default.
- W2055292893 modified "2023-09-26" @default.
- W2055292893 title "Effects of addition of rare-earth element on electrochemical characteristics of ZrNi1.1Mn0.5V0.3Cr0.1 hydrogen storage alloy electrodes" @default.
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- W2055292893 doi "https://doi.org/10.1016/s0925-8388(00)01496-1" @default.
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