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• W2055296871 abstract "Ordered planar morphologies in A-b-(B-b-A)2-b-C and (B-b-A)2-b-C terpolymer melts are studied within the framework of the self-consistent field theory for volume fractions of components A, B, and C in the ratio 1:1:2 and the Flory-Huggins interaction parameters satisfying χAB = 2χAC. The stable phases turn out to be the disordered, hexagonal, parallel lamellar-in-lamellar L∥ (including the simple lamellar) as well as non-shifted and shifted (L⊥ and SL⊥) perpendicular lamellar-in-lamellar morphologies. Depending on the value of the ratio r = ΘAB/ΘBC, where Θ is a characteristic temperature of the units involved, different sequences of phase transitions are shown to occur. The hexagonal phase is characteristic for r ≅ 1. The L⊥ and SL⊥ morphologies occur at weak and intermediate segregations whereas the L∥ morphology appears for stronger degrees of segregation. For (B-b-A)2-b-C a reduction in r favors the shifted SL⊥ phase over the non-shifted L⊥ one, whereas for A-b-(B-b-A)2-b-C we find re-entrant phase transitions SL⊥ − L⊥. The physics determining the particular phase behavior is discussed." @default.
• W2055296871 created "2016-06-24" @default.
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• W2055296871 date "2013-08-28" @default.
• W2055296871 modified "2023-10-09" @default.
• W2055296871 title "Perpendicular lamellar-<i>in</i>-lamellar and other planar morphologies in A-<i>b</i>-(B-<i>b</i>-A)2-<i>b</i>-C and (B-<i>b</i>-A)2-<i>b</i>-C ternary multiblock copolymer melts" @default.
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• W2055296871 doi "https://doi.org/10.1063/1.4818872" @default.
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• W2055296871 hasPublicationYear "2013" @default.
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