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- W2055321763 abstract "Abstract Charge transport rate and redox capacity have been studied with different electrochemical techniques on glassy carbon electrodes coated with thin crosslinked poly-4-vinylpyridine films containing either hexacyanoferrate or hexachloroiridate anions. Good agreement was found for the apparent diffusion coefficient when estimated with chronocoulometry and impedance spectroscopy. The redox capacity was determined with cyclic voltammetry and low frequency impedance measurements and good agreement was found at the polymer film electrodes containing hexacyanoferrate and hexachloroiridate at low concentrations. At higher concentrations of hexachloroiridate in the film, a smaller number of the redox sites seems to be electroactive in impedance spectroscopy than in cyclic voltammetry." @default.
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- W2055321763 date "1990-08-01" @default.
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- W2055321763 title "Ac-impedance studies of charge transport and redox capacities at poly-4-vinylpyridine films on electrode surfaces" @default.
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- W2055321763 doi "https://doi.org/10.1016/0022-0728(90)87208-2" @default.
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