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- W2055327240 abstract "The competition between geminate recombination of electrons with their parent radicals and electron scavenging with H+ is directly time resolved with ∼100 fs resolution at several acid concentrations. Electrons were produced from iodide photodetachment or two-photon ionization of H2O. With regards to those produced from iodide photodetachment, the separation between primary and secondary I:e− recombination is established using a full numerical solution to the diffusion equation. Electron ejection is found to be short range and a potential well of ∼3kbT depth stabilizing the solvent caged pair is required to yield a satisfactory fit to experiment. From time-resolved scavenging data up to 5 M HCl, it is shown that the electron can be scavenged both inside and outside the caged pair by H+ with nearly equal efficiency. The steady-state scavenging yield as a function of scavenger concentration is then predicted based on the determined time-dependent recombination function. Reassessment of several benchmark scavenging experiments from the 1960’s leads to the conclusion that the primary yield of electrons after excitation of iodide is near unity." @default.
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- W2055327240 date "2002-07-08" @default.
- W2055327240 modified "2023-09-25" @default.
- W2055327240 title "Time-resolved scavenging and recombination dynamics from I:e− caged pairs" @default.
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- W2055327240 doi "https://doi.org/10.1063/1.1483292" @default.
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