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- W2055352648 abstract "Cycloheptanol, cyclo-octanol, cyanoadamantane and cis-1,2-dimethylcyclohexane are known to form plastic crystals which can be supercooled to show a glass transition at a temperature Tg. The molecular dynamics in different plastic phases is studied in their supercooled states using dielectric spectroscopy (frequency range: 106 Hz–10−3 Hz) and differential scanning calorimetry (DSC) over a wide temperature range. The kinetic freezing of the various dielectric processes have been critically examined in relation to the Tg found in the DSC experiments. The plastic phase I of cyclo-octanol shows two Tg’s: one at 148.5 K and the other at 164 K, the former of which is not found in well annealed phase I. The dielectric α-modes correspond to the latter. Cycloheptanol exhibits many Tg’s for the different plastic phases. Unlike the cyclic alcohols, the dielectric spectra of cyanoadamantane and cis-1,2-dimethylcyclohexane is clearly found to follow the Havriliak–Negami equation, both of which interestingly show very little molecular mobility, often referred to as the secondary relaxation in their glassy states. In addition, the temperature dependence of the relaxation rates and the dielectric strengths are critically examined for various supercooled phases to gain an insight into the nature of the molecular mobility in those phases." @default.
- W2055352648 created "2016-06-24" @default.
- W2055352648 creator A5035159231 @default.
- W2055352648 creator A5075072257 @default.
- W2055352648 date "2001-02-22" @default.
- W2055352648 modified "2023-10-09" @default.
- W2055352648 title "Study of the nature of glass transitions in the plastic crystalline phases of cyclo-octanol, cycloheptanol, cyanoadamantane and cis-1,2-dimethylcyclohexane" @default.
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- W2055352648 doi "https://doi.org/10.1063/1.1342811" @default.
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