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- W2055362260 abstract "The HPLC resolution on a β-cyclodextrin column is reported of thirteen enantiomeric pairs of racemates of the type 6, 6′-μ-R-E(1,7-C2B9H10)2-2-Co with oxygen, sulphur and nitrogen bridges (E) and with a variety of R substituents differing in size and electronic properties along with structural factors influencing the capacity factors, selectivity and resolution of individual compounds. A semi-preparative method for chiral separations of these racemates is described and circular dichroism (CD) spectra of several pure enantiomers are presented. The CD spectra indicate the same absolute configurations of all enantiomers eluted first or last independent of the nature of the bridging atom and the size of the bridge substituting group R." @default.
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- W2055362260 date "1993-02-01" @default.
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- W2055362260 title "Chiral resolution of enantiomers of asymmetric cobaltacarboranes with a monoatomic bridge between ligands by liquid chromatography on a β-cyclodextrin column" @default.
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- W2055362260 doi "https://doi.org/10.1016/0021-9673(93)83139-j" @default.
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