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- W2055366489 abstract "The binary system EuEu2O3 has been examined in detail over the composition range EuO to Eu2O3 at 1500°C. Only three oxide phases were found: EuO, Eu3O4, and Eu2O3. Both EuO and Eu3O4 exhibit very narrow composition limits, while the monoclinic sesquioxide is stable over the composition range EuO1.45 to EuO1.50 at 1500°C. The melting points found for the three phases were 1900°C for EuO, 2000°C for Eu3O4 and 2300°C for Eu2O3. Europium was quantitatively extracted from EuO by reaction with platinum in sealed capsules at 1500°C, which resulted in the formation of an intermetallic phase plus a higher oxide of europium. The most europium-rich intermetallic phase found in these studies, EuPt2+x, has the fcc MgCu2 structure and is stable over the composition range EuPt2.0 to EuPt2.8 at 1500°C. Besides EuPt2, two phases were encountered in the EuPt alloys which contained more than 75 at.% Pt. These are tentatively designated as Eu2Pt7 and EuPt5. No crystalline phases other than the sesquioxides were found in the SmSm2O3 or the YbYb2O3 systems." @default.
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- W2055366489 date "1971-02-01" @default.
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- W2055366489 title "Investigations into the EuEu2O3, the EuPtEu2O3, the SmSm2O3, and the YbYb2O3 systems" @default.
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- W2055366489 doi "https://doi.org/10.1016/0022-4596(71)90014-4" @default.
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