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- W2055416758 abstract "Propargyl aldehyde complexes, (RC⋮CCHO)Co2(CO)6 (1a−c; R = Ph, Me, H), undergo pinacol coupling with a variety of reductants, exclusively giving syn (dl)-diacetylenic diol complexes 2a−c. The X-ray structures of 2a and 2c have been determined. The free diol syn-PhC⋮C−CH(OH)CH(OH)−C⋮CPh (4a) is obtained efficiently from its cobalt complex 2a upon treatment with (NH4)2Ce(NO3)6." @default.
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- W2055416758 date "2003-09-16" @default.
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- W2055416758 title "Stereoselective Pinacol Coupling of (Propargyl aldehyde)Co<sub>2</sub>(CO)<sub>6</sub> Complexes" @default.
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- W2055416758 doi "https://doi.org/10.1021/om030392t" @default.
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