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• W2055420068 abstract "An unusual k = [½ ½ ½] magnetic structure is reported in Sr2FeO3F at low temperature. The magnetic structures of LaBaFeO4, LaSrFeO4, LaCaFeO4, Ca2FeO3Cl, Ca2FeO3Br, Sr2FeO3F, Sr2FeO3Cl, Sr2FeO3Br and solid solutions in the series Sr2Fe1−xCoxO3Cl have been examined and only Sr2FeO3F exhibits this structure. The La2CuO4-type spin arrangement dominates in all these phases, with antiferromagnetic ordering in the xy planes. The k = [½ ½ ½] magnetic phase in Sr2FeO3F occurs below 100 K and requires La2CuO4-type stacking across the SrO layers and La2NiO4-type stacking across the SrF layers. It has been possible to show that this phase grows in domains which have purely La2CuO4-type stacking at higher temperatures. In the Sr2Fe1−xCoxO3Cl series the La2CuO4-type magnetic structure in Sr2FeO3Cl and the La2NiO4-type structure in Sr2CoO3Cl coexist and structural and magnetic behaviour indicate phase segregation into cobalt- and iron-rich regions." @default.
• W2055420068 created "2016-06-24" @default.
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• W2055420068 date "2005-01-01" @default.
• W2055420068 modified "2023-10-04" @default.
• W2055420068 title "An unusual magnetic structure in Sr2FeO3F and magnetic structures of K2NiF4-type iron(iii) oxides and oxide halides, including the cobalt substituted series Sr2Fe1–xCoxO3Cl" @default.
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• W2055420068 doi "https://doi.org/10.1039/b505617a" @default.
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