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• W2055429131 startingPage "335" @default.
• W2055429131 abstract "Abstract The electronic structure of amorphous diamond-like carbon is reviewed. The sp2 sites form small, mainly chain-like clusters which control the bandgap. Detailed analysis shows that all π states within the σ-σ* gap are all localized; so the mobility gap greatly exceeds the optical gap. This accounts for the photoluminescence excitation spectrum. Dangling-bond states are calculated to possess some s orbital character, which lowers their energy level in the gap and accounts for the p-type conduction of tetrahedral amorphous carbon. The defect density is high in hydrogenated amorphous carbon and is found to be fairly well described by the weak-bond-dangling-bond conversion model. The photoluminescence mechanism is described and it is argued that the paramagnetic defects are still the most likely dominant recombination centre." @default.
• W2055429131 created "2016-06-24" @default.
• W2055429131 creator A5056592766 @default.
• W2055429131 date "1997-09-01" @default.
• W2055429131 modified "2023-09-26" @default.
• W2055429131 title "Gap states in diamond-like amorphous carbon" @default.
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• W2055429131 doi "https://doi.org/10.1080/01418639708241098" @default.
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