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- W2055442662 abstract "Adducts of primary F-alkyl iodides with nickel carbonyl are formed readily in donor solvents and pyrolyze at 100−150 °C to give olefinic coupling products in high yield. The mechanism proposed to account for the observed chemistry involves preferential α-elimination of fluorine with formation of a carbenoid species complex coordinated to nickel. Differences in reaction paths among several types of substrate halides are rationalized on the basis of polarization of the Ni−C bond in the adducts. Support for these proposals is provided by state-of-the-art calculations." @default.
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- W2055442662 date "1998-01-01" @default.
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- W2055442662 title "Transformations of <i>F</i>-Alkyl Iodides and Bromides Induced by Nickel(0) Carbonyl" @default.
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- W2055442662 doi "https://doi.org/10.1021/jo970805y" @default.
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