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• W2055496783 abstract "Abstract The limited scheelite type Cd 1−3 x □ x Gd 2 x MoO 4 solid solution, where 0  x  ≤ 0.25 and □ are cationic vacancies have been successfully synthesized by high-temperature annealing of CdMoO 4 /Gd 2 (MoO 4 ) 3 mixtures composed of 50.00 mol.% and less of Gd 2 (MoO 4 ) 3 . The obtained materials as well as CdMoO 4 and Gd 2 (MoO 4 ) 3 were characterized by powder XRD, DTA–TG, DSC, and SEM techniques. A phase diagram of the pseudobinary CdMoO 4 –Gd 2 (MoO 4 ) 3 system was constructed. The eutectic point corresponds to 1350 ± 5 K and ∼70.00 mol.% of Gd 2 (MoO 4 ) 3 in an initial CdMoO 4 /Gd 2 (MoO 4 ) 3 mixture. With decreasing of Gd 3+ amount in the crystal lattice of CdMoO 4 , a melting point of the Cd 1−3 x □ x Gd 2 x MoO 4 solid solution increases from 1351 ( x  = 0.25) to 1408 K ( x  = 0). EPR method was used to identify the paramagnetic Gd 3+ centers in Cd 1−3 x □ x Gd 2 x MoO 4 for different values of x parameter as well as to select biphasic samples containing both Cd 0.2500 □ 0.2500 Gd 0.5000 MoO 4 and Gd 2 (MoO 4 ) 3 ." @default.
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• W2055496783 date "2014-06-01" @default.
• W2055496783 modified "2023-09-30" @default.
• W2055496783 title "Thermal and magnetic properties of new scheelite type Cd1−3x□xGd2xMoO4 ceramic materials" @default.
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• W2055496783 doi "https://doi.org/10.1016/j.jeurceramsoc.2013.12.015" @default.
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