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- W2055514824 abstract "L'effet de différents anions sur la formation et la rupture du film d'oxyde sur une électrode d'aluminium, a été étudié au moyen de mesures potentiostatiques quasi-stationnaires et transitoires, associées avec des analyses de la surface du métal par la spectrométrie de photo-électrons. Une incorporation progressive des ions Cl− dans la couche d'oxyde, en fonction du potentiel de l'électrode, a été mise en évidence. Il a été montré également que les ions ClO−4 sont réduits quantitativement à l'interface oxydesolution. The effect of different anions on the formation and the breakdown of the passivating film on aluminium was studied by means of stationary and transient potentiostatic measurements associated with analysis of the surface region of the metal by photoelectron spectrometry (ESCA). The progressive penetration of chloride ions into the oxide layer, dependent on the electrode potential was pointed out. The perchlorate ion was shown to be reduced at the film-solution interface." @default.
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- W2055514824 date "1975-10-01" @default.
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- W2055514824 title "Etude potentiostatique et spectroscopique de l'aluminium recouvert par une couche d'oxyde: effet de differents anions" @default.
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- W2055514824 doi "https://doi.org/10.1016/0013-4686(75)85009-2" @default.
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