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- W2055520359 abstract "Benzene, in 20−30 bar of hydrogen, reacts smoothly in a quartz tubular flow reactor between 1163−1262 K, to give high yields of methane. With dwell times of 3−23 s, degrees of conversion ranged from 10 to 95%. Substituents such as Cl and CH3 are displaced more easily: ca. 350 times more rapidly at 1250 K. Mechanisms are discussed on a quantitative thermochemical-kinetic basis. Of the alternatives considered, only a pathway through H atom addition, (reversible) isomerisation of C6H7· species, H-transfer from H2 to give − for example − methylcyclopentadiene (F), followed by splitting into ·CH3 and cyclopentadienyl radical (G), would fully explain the observed rates of conversion of benzene." @default.
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- W2055520359 date "2001-06-01" @default.
- W2055520359 modified "2023-09-24" @default.
- W2055520359 title "Gas-Phase Hydrogenolysis of Benzene and Derivatives at Elevated Pressure; Methane Formation" @default.
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- W2055520359 doi "https://doi.org/10.1002/1099-0690(200106)2001:11<2101::aid-ejoc2101>3.0.co;2-e" @default.
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