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- W2055536924 abstract "Analogy with the isolable oxo cluster [Fe3(CO)9(μ3-O)]2−, which is structurally interesting and synthetically useful, prompted the present attempt to synthesize its ruthenium analog. Although the high reactivity of [Ru3(CO)9(μ3-O)]2− (I) prevented its isolation, the reaction of this species with [M(CO)3(NCCH3)]+, where M = Mn or Re, yields [PPN][MRu3(CO)12(η2-μ3-NC(μ-O)CH3]−. The high nucleophilicity of the oxo ligand in [Ru3(CO)9(μ3-O)]2− (I) appears to be responsible for the conversion of acetonitrile to an acetamidediato ligand and for the instability of I. The crystal structure of [PPN][MnRu3(CO)12(η2-μ3-NC(μ-O)CH3)]] reveals a hinged butterfly array of metal atoms in which the acetamidediato ligand bridges the two wings with μ3-N bonding to an Mn and two Ru atoms, and μ-O bonding to an Ru atom." @default.
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- W2055536924 date "1995-12-01" @default.
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- W2055536924 title "Mixed-metal butterfly acetamidediato clusters derived from a highly reactive ruthenium oxo cluster: synthesis and characterization of [(PPh3)2N][MRu3(CO)12(η2-μ3-NC(μ-O)CH3)], (M = Mn or Re)" @default.
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- W2055536924 doi "https://doi.org/10.1016/0020-1693(95)04515-5" @default.
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