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- W2055547368 abstract "Theoretical models for describing the kinetics of fullerene cluster growth in C60 solutions in N-methyl-2-pyrrolidone (NMP) are presented. First, a detailed review of current state of experimental investigation of C60/NMP is given. The relation between C60–NMP complex formation, cluster growth and their impact on solvatochromism is discussed. Next, a theoretical approach for description of cluster growth, based on kinetic equations of segregation, is proposed. Two modifications of basic approach are given. First one treats cluster growth in a supersaturated solution of C60, where new complex formation eventually limits growth of aggregates. In the second model a two-step process of cluster growth is considered: complex formation and cluster growth. The solution of C60–NMP complexes is supersaturated, while initial, “free” C60 does not aggregate. For each model a procedure for obtaining parameters is proposed and the parameter values are estimated." @default.
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- W2055547368 date "2012-11-01" @default.
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- W2055547368 title "Kinetics of cluster growth in polar solutions of fullerene: Experimental and theoretical study of C60/NMP solution" @default.
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- W2055547368 doi "https://doi.org/10.1016/j.molliq.2012.08.003" @default.
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