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- W2055592439 abstract "(R)-4-(Alkylthiomethyl)-5,5-dimethyl-2-(2′-hydroxyphenyl)-2-oxazolines are demonstrated to be highly suitable chiral auxiliaries for the two-step conversion of the half-sandwich complex [Ru(η6-C6H6)(bpy)Cl]Cl, bpy = 2,2′-bipyridine, into Δ-configured ruthenium polypyridyl complexes. The tailored thioether substituent at the oxazoline ring is essential for this conversion and not only promotes the removal of the benzene moiety but also controls the absolute metal-centered configuration. Applied to osmium, this strategy resulted in the first highly asymmetric synthesis of Δ-[Os(bpy)3](PF6)2." @default.
- W2055592439 created "2016-06-24" @default.
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- W2055592439 date "2013-01-01" @default.
- W2055592439 modified "2023-10-12" @default.
- W2055592439 title "Thioether-based anchimeric assistance for asymmetric coordination chemistry with ruthenium(ii) and osmium(ii)" @default.
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- W2055592439 doi "https://doi.org/10.1039/c3dt00015j" @default.
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