FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2055596592> ?p ?o ?g. }

• W2055596592 endingPage "9417" @default.
• W2055596592 startingPage "9407" @default.
• W2055596592 abstract "A new class of 1,3-disubstituted-triazenes were synthesized by coupling functionalized benzimidazol-2-ylidenes, as their free N-heterocyclic carbenes or generated in situ from their respective benzimidazolium precursors, to various aryl azides in modest to excellent isolated yields (36-99%). Electron delocalization between the two coupled components was studied using UV-vis spectroscopy, NMR spectroscopy, and X-ray crystallography. Depending on the complementarity of the functional groups on the N-heterocyclic carbenes and the organic azides, the respective triazenes were found to exhibit lambda(max) values ranging between 364 and 450 nm. X-ray crystallography revealed bond alteration patterns in a series of triazenes characteristic of donor-acceptor compounds. Triazene thermal stabilities were studied using thermogravimetric analysis and found to be strongly dependent on the sterics of the benzimidazol-2-ylidene component and the electronics of the azide component. Triazenes possessing bulky N-substituents (e.g., neo-pentyl, tert-butyl, etc.) were stable in the solid-state to temperatures exceeding 150 degrees C, whereas analogues with small N-substituents (e.g., methyl) were found to slowly decompose at room temperature. Triazenes featuring electron-rich phenyl azide components decomposed at higher temperatures than their electron-deficient analogues. Products of the thermally induced triazene decomposition reaction were identified as molecular nitrogen and the respective guanidine. Using an isotopically labeled triazene, the mechanism of the decomposition reaction was found to be analogous to the Staudinger reaction." @default.
• W2055596592 created "2016-06-24" @default.
• W2055596592 creator A5078166911 @default.
• W2055596592 creator A5084310453 @default.
• W2055596592 date "2007-07-03" @default.
• W2055596592 modified "2023-10-16" @default.
• W2055596592 title "Donor−Acceptor Triazenes: Synthesis, Characterization, and Study of Their Electronic and Thermal Properties" @default.
• W2055596592 cites W1902936547 @default.
• W2055596592 cites W1968652549 @default.
• W2055596592 cites W1971539541 @default.
• W2055596592 cites W1973412930 @default.
• W2055596592 cites W1974396710 @default.
• W2055596592 cites W1974659074 @default.
• W2055596592 cites W1975478493 @default.
• W2055596592 cites W1999387838 @default.
• W2055596592 cites W2000164249 @default.
• W2055596592 cites W2000336362 @default.
• W2055596592 cites W2001704521 @default.
• W2055596592 cites W2008081756 @default.
• W2055596592 cites W2010608019 @default.
• W2055596592 cites W2011114105 @default.
• W2055596592 cites W2012013137 @default.
• W2055596592 cites W2016700878 @default.
• W2055596592 cites W2020898358 @default.
• W2055596592 cites W2022675473 @default.
• W2055596592 cites W2026372047 @default.
• W2055596592 cites W2029563489 @default.
• W2055596592 cites W2032396389 @default.
• W2055596592 cites W2032699736 @default.
• W2055596592 cites W2041044444 @default.
• W2055596592 cites W2043716459 @default.
• W2055596592 cites W2043775973 @default.
• W2055596592 cites W2044258609 @default.
• W2055596592 cites W2046286719 @default.
• W2055596592 cites W2046627076 @default.
• W2055596592 cites W2049407842 @default.
• W2055596592 cites W2049551421 @default.
• W2055596592 cites W2050924960 @default.
• W2055596592 cites W2051606102 @default.
• W2055596592 cites W2064521757 @default.
• W2055596592 cites W2065599740 @default.
• W2055596592 cites W2068614549 @default.
• W2055596592 cites W2077185308 @default.
• W2055596592 cites W2085445299 @default.
• W2055596592 cites W2086683168 @default.
• W2055596592 cites W2087376589 @default.
• W2055596592 cites W2088260283 @default.
• W2055596592 cites W2093530361 @default.
• W2055596592 cites W2135397988 @default.
• W2055596592 cites W2136266365 @default.
• W2055596592 cites W2145662716 @default.
• W2055596592 cites W2154705832 @default.
• W2055596592 cites W2163292258 @default.
• W2055596592 cites W2175533617 @default.
• W2055596592 cites W2289234576 @default.
• W2055596592 cites W2326686131 @default.
• W2055596592 cites W2335946667 @default.
• W2055596592 cites W2506395849 @default.
• W2055596592 cites W2950054586 @default.
• W2055596592 cites W2950860649 @default.
• W2055596592 cites W2951901527 @default.
• W2055596592 cites W2952168504 @default.
• W2055596592 cites W2952533572 @default.
• W2055596592 cites W2953354816 @default.
• W2055596592 cites W4251334424 @default.
• W2055596592 cites W4256503849 @default.
• W2055596592 cites W2121748487 @default.
• W2055596592 doi "https://doi.org/10.1021/jo070789x" @default.
• W2055596592 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17608438" @default.
• W2055596592 hasPublicationYear "2007" @default.
• W2055596592 type Work @default.
• W2055596592 sameAs 2055596592 @default.
• W2055596592 citedByCount "83" @default.
• W2055596592 countsByYear W20555965922012 @default.
• W2055596592 countsByYear W20555965922013 @default.
• W2055596592 countsByYear W20555965922014 @default.
• W2055596592 countsByYear W20555965922015 @default.
• W2055596592 countsByYear W20555965922016 @default.
• W2055596592 countsByYear W20555965922017 @default.
• W2055596592 countsByYear W20555965922018 @default.
• W2055596592 countsByYear W20555965922019 @default.
• W2055596592 countsByYear W20555965922020 @default.
• W2055596592 countsByYear W20555965922021 @default.
• W2055596592 countsByYear W20555965922022 @default.
• W2055596592 countsByYear W20555965922023 @default.
• W2055596592 crossrefType "journal-article" @default.
• W2055596592 hasAuthorship W2055596592A5078166911 @default.
• W2055596592 hasAuthorship W2055596592A5084310453 @default.
• W2055596592 hasConcept C155647269 @default.
• W2055596592 hasConcept C160434732 @default.
• W2055596592 hasConcept C178790620 @default.
• W2055596592 hasConcept C185592680 @default.
• W2055596592 hasConcept C2780242487 @default.
• W2055596592 hasConcept C2780263894 @default.
• W2055596592 hasConcept C2780997848 @default.
• W2055596592 hasConcept C2781076698 @default.
• W2055596592 hasConcept C60100273 @default.
• W2055596592 hasConcept C70050531 @default.

• next