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- W2055623403 abstract "Abstract Various arene‐Cr (CO) 3 complexes and Cr(CO) 6 are effective soluble catalysts for the conjugation of polyunsaturated fats. Methyl benzoate‐Cr(CO) 3 is one of the most active catalysts. The following conjugation levels were obtained: methyl linoleate, 65%; methyl linolenate, 45%; the polyunsaturates in soybean and safflower oils, 73%; and in linseed oil 48%. Conjugated dienes from linoleate were predominantly cis,trans in configuration. Their double bonds were distributed between C 5 and C 16 of the fatty acid chain. Hydrogenation and dehydrogenation are side reactions, which seem to limit the yield of conjugated dienes from methyl linoleate. A conjugation mechanism is proposed that involves allyl‐HCr(CO) 3 complexes as intermediates undergoing 1,3‐ and 1,5‐hydrogen shifts." @default.
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- W2055623403 date "1970-02-01" @default.
- W2055623403 modified "2023-10-14" @default.
- W2055623403 title "Homogenous catalytic conjugation of polyunsaturated fats by chromium carbonyls" @default.
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- W2055623403 doi "https://doi.org/10.1007/bf02541453" @default.
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