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- W2055694580 abstract "A novel water-soluble copolymer of aniline and aminophenol (AP) grafted with oligo(oxyethylene) (PEO) side chains (AP-g-PEO) was synthesized. The AP-g-PEO macromononer was prepared starting from an N-protected 3-aminophenol (protection group: tert-butoxycarbonyl) followed by the substitution of tosylated oligo(oxyethylene) on the hydroxide moiety of the AP and deprotection. Finally, AP-g-PEO was copolymerized with aniline at various feed mole ratios (AP-g-PEO/aniline). The copolymers and various intermediates were characterized by FTIR, MS, NMR, GPC, UV−vis, and chemical elemental analysis. The increase of the aniline content and the decrease of the PEO side chain length generated lower oligo(oxyethylene) grafted concentrations and solubilities in water but longer conjugation lengths and higher conductivities. Four AP-g-PEOs were prepared from four oligo(oxyethylene) methyl ethers with Mn = 164, 350, 750, and 2000. The poly((AP-g-PEO-750)-co-aniline) at a feed mole ratio of 3/1 was water-soluble and poss..." @default.
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- W2055694580 date "2004-07-09" @default.
- W2055694580 modified "2023-10-17" @default.
- W2055694580 title "Copolymers of Aniline and 3-Aminophenol Derivatives with Oligo(oxyethylene) Side Chains as Novel Water-Soluble Conducting Polymers" @default.
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- W2055694580 doi "https://doi.org/10.1021/ma040070g" @default.
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