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• W2055763286 startingPage "5336" @default.
• W2055763286 abstract "In the present work, a novel stereoselective radical cyclization/oxidation/spirocyclization cascade process using a mixture of n-Bu3SnH/ dilauroyl peroxide is described. The proposed mechanism for this later process combines a 6-endo cyclization of an aryl radical onto an enamide double bond, and a consecutive oxidative-ionic spirocyclization at C-3 of an indole nucleus. All processes led to the construction of new spiroindolenine derivatives in a one-step synthesis starting from relatively simple starting materials. The organic peroxide appears to act as the initiator and the oxidant." @default.
• W2055763286 created "2016-06-24" @default.
• W2055763286 creator A5049306684 @default.
• W2055763286 creator A5062915089 @default.
• W2055763286 date "2009-09-01" @default.
• W2055763286 modified "2023-10-03" @default.
• W2055763286 title "Synthesis of spiroindolenine derivatives by a tandem radical-oxidation process" @default.
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• W2055763286 doi "https://doi.org/10.1016/j.tetlet.2009.07.037" @default.
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