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• W2055812614 abstract "This paper reports on an approach to control molecular stacking interactions in low-dimensional mixed valence materials by locking partially oxidized metallomacrocycles together in a cofacial orientation. Iodine doping of the face-to-face linked oligomers [M(Pc)O]n (M = Si, Ge, Sn; Pc = phthalocyaninato) produces electrically conductive polymers {[M(Pc)O]Ixn with a wide range of x stoichiometries. Resonance Raman spectroscopy indicates that the iodine has oxidized the polymer chain. Polymer structure has been studied by X-ray powder diffraction, and it is possible to estimate interplanar spacings. Halogen doping of the [M(Pc)O]n materials is accompanied by electrical conductivity increases as large 107 (ohm cm)−1; the general trend is σSi ⪆ σGe > σSn. Variable temperature conductivity and magnetic susceptibility data are reported." @default.
• W2055812614 created "2016-06-24" @default.
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• W2055812614 date "1980-04-01" @default.
• W2055812614 modified "2023-09-26" @default.
• W2055812614 title "New conductive polymeric materials: Cofacial assembly of mixed valent metallomacrocycles" @default.
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• W2055812614 doi "https://doi.org/10.1016/0379-6779(80)90023-5" @default.
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