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• W2055824612 abstract "The Gibbs energy of formation of Rb2ThO3(s) has been determined using manometric technique. The equilibrium CO2(g) pressures over the three phase mixture: {Rb2ThO3(s)+ Rb2CO3(s) + ThO2(s)} have been measured using differential oil manometer in the temperature range 952–1098 K. The corresponding Gibbs energy expression as a function of temperature is given by: ΔfGm°(Rb2ThO3,s,T) (kJ mol−1) ± 23 = −1691.4 + 0.280 T(K). The ΔfGm°(T) and ΔfHm°(298.15 K) values have been estimated for alkali and alkaline earth metal thorates. An estimation method has also been developed for ΔfHm°(AMO3,s, 298.15 K), where A represents Li2, Na2, K2, Rb2, Cs2, Ca, Sr and Ba and M represents Am, Ce, Cf, Cm, Cr, Ge, Ir, Mo, Np, Pb, Ru, Se, Sn. Tb, Te, Th, C, Hf, N, Pr, Pt, Rh, Si, Ti and Zr." @default.
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• W2055824612 date "2005-08-01" @default.
• W2055824612 modified "2023-10-14" @default.
• W2055824612 title "Thermodynamic studies on Rb2ThO3(s)" @default.
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• W2055824612 doi "https://doi.org/10.1016/j.jallcom.2005.02.007" @default.
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