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- W2055837370 abstract "The retention behaviour of amines was investigated in systems with silica gel (LiChrosorb Si 60) as the support and an aqueous phosphate buffer containing organic modifiers as the mobile phase. N,N-Dimethyloctylamine and N,N,N-trimethyloctylamine were used as cationic modifiers, with 3,5-dimethylcyclohexylsulphate as the ion-pair forming counter ion. Adsorption isotherms were determined for the amines used as modifiers. At low concentrations of modifier a monolayer is formed on the solid phase and the retention times of the solutes decrease with increasing modifier concentration. Higher concentrations give rise to the formation of a multilayer or bulk phase of modifier, leading to rapidly increased retention of the most hydrophobic solutes and a change in retention order. They hydrogen-bonding properties of the solute seem to be of major importance for the retention on unmodified silica, while the hydrophobicity of the solute determines the retention to the adsorbed phase of the modifier." @default.
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- W2055837370 date "1982-08-01" @default.
- W2055837370 modified "2023-09-25" @default.
- W2055837370 title "Liquid chromatography of substituted phenoxypropanolamines on dynamically coated silica using aqueous mobile phases" @default.
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- W2055837370 doi "https://doi.org/10.1016/s0021-9673(00)82473-5" @default.
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