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• W2055849300 abstract "Charging of particles in aqueous suspensions is primarily related to potential determining ions, such as silver and iodide ions at silver halide particle surfaces. Proton is considered as a (secondary) potential determining ion at hydrated metal oxide surfaces. Indifferent electrolytes neutralize at increased concentration the surface charge but do not reverse it. However, in the presence of a non-Coulombic interaction the surface charge may be enhanced or reversed at increased ionic strength. Such interaction is denoted specific which may be due to enhanced van der Waals dipolar, Lewis acid-base, solvation (Hofmeister) and/or Born solvation effects. Alternatively, these interactions have been characterized in terms of (semi) empirical ion and surface properties, such as hard-soft acid-base (HSAB) interaction. Within the Stern layer closest to the particle surface truly specific effects are related to the inner Helmholtz plane (IHP) in order to distinguish them from the charge and solvation related effects occurring within the outer Helmholtz plane (OHP). We review some recent observations on the particular influence of ions on the charging of titania particles in aqueous 1:1, 2:1, 1:2 and mixed electrolyte suspensions." @default.
• W2055849300 created "2016-06-24" @default.
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• W2055849300 date "2012-11-01" @default.
• W2055849300 modified "2023-09-25" @default.
• W2055849300 title "Peculiar charging effects on titania in aqueous 1:1, 2:1, 1:2 and mixed electrolyte suspensions" @default.
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• W2055849300 doi "https://doi.org/10.1016/j.cis.2012.06.014" @default.
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