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- W2055868008 abstract "Abstract Internal olefins are hydroformylated to linear aldehydes in substantial amounts with the cationic platinum/tin catalyst system PtCl(CO)(PR 3 ) 2 + /SnCl 2 . By altering the nature of the phosphine ligand, as well as the various reaction conditions, the selectivity for terminal aldehyde production can be widely varied. Three competing processes, substrate hydroformylation, isomerization, and hydrogenation, are found to take place. The overall reaction is highly sensitive to syn gas pressure; however, total aldehyde selectivity and aldehyde linearity have opposite pressure dependences, rendering predominant normal aldehyde formation difficult." @default.
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- W2055868008 date "1982-02-01" @default.
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- W2055868008 title "Homogeneous hydroformylation of internal olefins by platinum/tin cationic complexes" @default.
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- W2055868008 doi "https://doi.org/10.1016/0304-5102(82)80040-0" @default.
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