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• W2055913275 abstract "Nine mixed crystals combined 1,4-benzoquinone (1), 2,5-xyloquinone (2) and duroquinone (3) with durene (a), pentamethylbenzene (b) and hexamethylbezene (c) were prepared by a melting-resolidifying process and characterized by powder X-ray diffractometry, DSC and IR. Only the mixed crystal of 3 and a formed a 2:1 novel molecular crystal (4); other eight mixed crystals were simple polycrystalline mixtures of the two components. Irradiation of the molecular crystal 4 (3/a) and the mixed crystals 1/a, 1/b and 3/b caused intermolecular hydrogen abstraction to give hydroquinones and in some cases adducts. Product selectivities in the solid state were different from those in solution. Correlation between the crystal structure and the reactivity of 4 is discussed." @default.
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• W2055913275 date "1994-01-01" @default.
• W2055913275 modified "2023-10-11" @default.
• W2055913275 title "Solid-state photochemistry of the mixed crystals between benzoquinones and polymethylbenzenes" @default.
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• W2055913275 doi "https://doi.org/10.1016/s0040-4020(01)85676-3" @default.
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