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- W2055939084 abstract "- 2-Chloropyridines, bearing a CF3 group on position 3, 4, 5 or 6 (2-Cl Py CF3) were found to be suitable substrates for photostimulated SRN1 reactions with nucleophiles derived from 2-naphthol (Nap-OH) or from phenol (PhOH). Carbon-carbon coupling between the regiospecifically generated 2-pyridyl radical and the carbanionic site of the nucleophile yields 2-heterobiaryl derivatives (CF3Py-Nap-OH or CF3Py-PhOH). Similarly, coupling of the 2-amino-5-CF3-3-pyridyl radical yields 3-heterobiaryl derivatives. Coupling of the malonate anion takes place with the aforementioned radicals." @default.
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- W2055939084 date "1993-09-03" @default.
- W2055939084 modified "2023-10-11" @default.
- W2055939084 title "SRN1 reactions of chlorotrifluoromethyl pyridines with naphtholate, phenolate and malonate anions" @default.
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- W2055939084 doi "https://doi.org/10.1016/s0040-4020(01)88013-3" @default.
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