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- W2056019211 abstract "While most thermodynamic properties refer to individual fluid phases, interfacial tension (IFT) is unique in the sense that it is a property of the interface between the fluid phases. The IFT, being a sensitive property strongly dependent on the composition of the interacting phases, is a good indicator of mass transfer effects between the phases. Furthermore, a condition of zero interfacial tension is essential to attain miscibility of the fluid phases in contact. Based on this concept, a new technique of vanishing interfacial tension (VIT) has been reported recently for experimental determination of fluid–fluid miscibility. Similar to the VIT technique in concept, a computational model based on parachor IFT calculations has been proposed in the present study for miscibility prediction. This model has been compared with VIT experiments and EOS calculations. For this purpose, Rainbow Keg River (RKR) reservoir fluids have been used, since the phase behaviour data necessary for miscibility calculations and the VIT experimental results were readily available. The parachor computational model resulted in over-predictions of miscibility when compared to VIT experiments and EOS calculations. These over predictions appear to be due to the inability of the parachor model to account for counter-directional mass transfer effects that can occur in reality between the fluids. Thus, in addition to demonstrating the importance of counter-directional mass transfer effects on fluid–fluid miscibility, this study has identified the need to incorporate these mass transfer effects in the proposed parachor computational model to compute fluid–fluid miscibility." @default.
- W2056019211 created "2016-06-24" @default.
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- W2056019211 date "2004-05-22" @default.
- W2056019211 modified "2023-10-07" @default.
- W2056019211 title "Application of the parachor model to the prediction of miscibility in multi-component hydrocarbon systems" @default.
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- W2056019211 doi "https://doi.org/10.1088/0953-8984/16/22/017" @default.
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