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- W2056030106 abstract "To gain a clear understanding of ferroelectricity and antiferroelectricity together with their frustration in chiral tilted smectic liquid crystals, we have constructed E–T phase diagrams by drawing field-induced birefringence contours in the prototype binary mixture system of MHPOCBC and MHPOOCBC. The results obtained are discussed in terms of the theoretical model proposed by Emelyanenko and Osipov; we have insisted on the appropriateness of specifying the biaxial subphases, which emerge sequentially in the temperature-induced transition, by the relative ratio of ferroelectric and antiferroelectric orderings in the superstructure unit cell, such as , where qT = [F]/([A] + [F]). Additional subphases other than the ordinary subphases with three- and four-layer superstructures, and , have been established to exist, firmly for and less adequately for and . Likewise, we have observed several stable superstructures during the field-induced transition from the biaxial subphases to unwound SmC*, and have tried to specify them using qE = |[R] − [L]|/([R] + [L]), where [R] and [L] refer to the numbers of smectic layers with directors tilted to the right and to the left, respectively, in a unit cell of the superstructure. We have also found the characteristic field-induced deformation of the uniaxial subphase and attempted to understand it in terms of the devil's staircase due to soliton condensation reported recently by Torikai and Yamashita ( 41 Torikai, M. and Yamashita, M. 2007. Mol. Cryst. Liq. Cryst., 465: 239–247. [Taylor & Francis Online], [Web of Science ®] , [Google Scholar])." @default.
- W2056030106 created "2016-06-24" @default.
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- W2056030106 date "2009-08-26" @default.
- W2056030106 modified "2023-10-16" @default.
- W2056030106 title "Degeneracy lifting near the frustration points due to long-range interlayer interaction forces and the resulting varieties of polar chiral tilted smectic phases" @default.
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- W2056030106 doi "https://doi.org/10.1080/02678290902815434" @default.
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