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- W2056070027 endingPage "107" @default.
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- W2056070027 abstract "The α-fluorovinyltriphenylphosphonium triflate 4 is prepared in high yields by the diphenylphosphinylation of 1,1-difluoroethylene 1 and subsequent quaternization of the phosphine 2 with diphenyliodonium triflate in the presence of CuCl. The salt 4 then undergoes Michael addition followed by Wittig olefination to give the corresponding monofluoroethylene compounds in good yields. The reaction of 4 with the caesium salts of salicylaldehyde derivatives in DMF at 130 °C affords the corresponding monofluorinated chromenes in a one-pot synthesis. The hydrolysis of 4 in the presence of sodium hydroxide gives triphenylphosphine oxide in quantitative yield." @default.
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- W2056070027 date "2000-01-01" @default.
- W2056070027 modified "2023-10-03" @default.
- W2056070027 title "Synthesis and reactions of α-fluorovinylphosphonium salts" @default.
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- W2056070027 doi "https://doi.org/10.1039/a905878h" @default.
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