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- W2056076000 abstract "The first transition series diborides are isomorphous compounds from ScB2 to MnB2. They all show metallic behaviour and are paramagnetic up to VB2; CrB2, on the opposite, is antiferromagnetic (TN = 86 K) with a small magnetic moment value in the ordered state which suggests the occurrence of itinerant spin magnetism. Heat capacity measurements on V1−xCrxB2 show a sharp maximum of the electronic specific heat for x ∼ 0.8, correlated with the onset of long-range antiferromagnetic ordering as given by magnetic susceptibility measurements. The existence of local effects cannot explain by itself the observed specific heat enhancement. The existence of similar phenomena in the isoelectronic Mo1-xCrxB2 alloys suggests that large amplitude spin fluctuations contribute to the renormalization of the one electron energies in a significant way. The free energy of the electron gas is computed in the R.P.A. Only intraatomic interactions are taken into account. It is shown that various phenomenological models are capable of yielding a significant spin fluctuation effect." @default.
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- W2056076000 date "1972-01-01" @default.
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- W2056076000 title "Spin fluctuation effects in nearly antiferromagnetic vanadium and chromium diborides" @default.
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- W2056076000 doi "https://doi.org/10.1016/0022-3697(72)90035-2" @default.
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