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- W2056105459 abstract "A CO2 TEA laser is used to generate PO radical by infrared multiphoton dissociation of dimethyl methylphosphonate in an excess of oxygen at total pressures up to 1.4 Torr. The pseudo-first-order reactive decay of PO (v″=0) is followed by laser-induced fluorescence utilizing its A 2Σ+–X 2Π transition. A bimolecular rate constant of 1.4 (±0.2)×10−11 cc/molecule/s is measured for the PO+O2 reaction. Earlier measurements of a much slower rate in flow discharge systems may be complicated by the establishment of equilibrium between the forward and reverse reactions PO+O2↔PO2+O." @default.
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- W2056105459 date "1986-05-15" @default.
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- W2056105459 title "Rate constant for the reaction of PO radical with oxygen" @default.
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- W2056105459 doi "https://doi.org/10.1063/1.450783" @default.
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