Matches in SemOpenAlex for { <https://semopenalex.org/work/W2056119011> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W2056119011 endingPage "2990" @default.
- W2056119011 startingPage "2985" @default.
- W2056119011 abstract "Thermochromic and solvatochromic equilibria involving the ions [Ni(tmen)(acac)]+ and [Cu(tmen)(acac)]+ respectively are highly sensitive to the polarity of the solvent. These probes are thus suited for the study of binary mixtures. In nitromethane (NM)/dimethylformamide (DMF) binary solvent the Ni(II) complex displays strong thermochromism in a zone of low DMF concentration. This result is surprising because neither of the two solvents are intrinsically thermochromic since NM is a weak donor while DMF is a strong donor. NM/DMF binary mixtures behave like solvents with intermediate donor properties. In the same solvent mixtures (low DMF concentration), the solvatochromic behavior of the Cu(II) complex is reflected by a large shift in the maximum absorption of more than 70 nm. This was accounted for by the considerable variation in donor power of the solvent mixture in this concentration range. Quantitative analysis of the thermochromic and solvatochromic equilibria as a function of DMF concentration in NM ..." @default.
- W2056119011 created "2016-06-24" @default.
- W2056119011 creator A5010784641 @default.
- W2056119011 creator A5031826296 @default.
- W2056119011 creator A5041951651 @default.
- W2056119011 creator A5053196080 @default.
- W2056119011 creator A5085810071 @default.
- W2056119011 date "1990-10-01" @default.
- W2056119011 modified "2023-10-15" @default.
- W2056119011 title "Strong Thermochromic and Solvatochromic Effects of Ni(II) and Cu(II) Complexes in DMF/Nitromethane Mixtures: A Probe for Investigation of Binary Solvent" @default.
- W2056119011 cites W1977771128 @default.
- W2056119011 cites W1978469574 @default.
- W2056119011 cites W2006157852 @default.
- W2056119011 cites W2006488933 @default.
- W2056119011 cites W2008277990 @default.
- W2056119011 cites W2014225184 @default.
- W2056119011 cites W2021998329 @default.
- W2056119011 cites W2029511765 @default.
- W2056119011 cites W2038948941 @default.
- W2056119011 cites W2051139187 @default.
- W2056119011 cites W2053419323 @default.
- W2056119011 cites W2061447311 @default.
- W2056119011 cites W2076228701 @default.
- W2056119011 cites W2076555939 @default.
- W2056119011 cites W2321877117 @default.
- W2056119011 cites W2326838331 @default.
- W2056119011 cites W4244646540 @default.
- W2056119011 doi "https://doi.org/10.1246/bcsj.63.2985" @default.
- W2056119011 hasPublicationYear "1990" @default.
- W2056119011 type Work @default.
- W2056119011 sameAs 2056119011 @default.
- W2056119011 citedByCount "9" @default.
- W2056119011 countsByYear W20561190112014 @default.
- W2056119011 countsByYear W20561190112023 @default.
- W2056119011 crossrefType "journal-article" @default.
- W2056119011 hasAuthorship W2056119011A5010784641 @default.
- W2056119011 hasAuthorship W2056119011A5031826296 @default.
- W2056119011 hasAuthorship W2056119011A5041951651 @default.
- W2056119011 hasAuthorship W2056119011A5053196080 @default.
- W2056119011 hasAuthorship W2056119011A5085810071 @default.
- W2056119011 hasBestOaLocation W20561190111 @default.
- W2056119011 hasConcept C132439834 @default.
- W2056119011 hasConcept C178790620 @default.
- W2056119011 hasConcept C179104552 @default.
- W2056119011 hasConcept C185592680 @default.
- W2056119011 hasConcept C194365794 @default.
- W2056119011 hasConcept C2777327210 @default.
- W2056119011 hasConcept C2780471494 @default.
- W2056119011 hasConcept C33923547 @default.
- W2056119011 hasConcept C48372109 @default.
- W2056119011 hasConcept C67218372 @default.
- W2056119011 hasConcept C75473681 @default.
- W2056119011 hasConcept C94375191 @default.
- W2056119011 hasConceptScore W2056119011C132439834 @default.
- W2056119011 hasConceptScore W2056119011C178790620 @default.
- W2056119011 hasConceptScore W2056119011C179104552 @default.
- W2056119011 hasConceptScore W2056119011C185592680 @default.
- W2056119011 hasConceptScore W2056119011C194365794 @default.
- W2056119011 hasConceptScore W2056119011C2777327210 @default.
- W2056119011 hasConceptScore W2056119011C2780471494 @default.
- W2056119011 hasConceptScore W2056119011C33923547 @default.
- W2056119011 hasConceptScore W2056119011C48372109 @default.
- W2056119011 hasConceptScore W2056119011C67218372 @default.
- W2056119011 hasConceptScore W2056119011C75473681 @default.
- W2056119011 hasConceptScore W2056119011C94375191 @default.
- W2056119011 hasIssue "10" @default.
- W2056119011 hasLocation W20561190111 @default.
- W2056119011 hasOpenAccess W2056119011 @default.
- W2056119011 hasPrimaryLocation W20561190111 @default.
- W2056119011 hasRelatedWork W2030910429 @default.
- W2056119011 hasRelatedWork W2034540003 @default.
- W2056119011 hasRelatedWork W2040177023 @default.
- W2056119011 hasRelatedWork W2056119011 @default.
- W2056119011 hasRelatedWork W2061650771 @default.
- W2056119011 hasRelatedWork W2078518204 @default.
- W2056119011 hasRelatedWork W2087367806 @default.
- W2056119011 hasRelatedWork W2149934411 @default.
- W2056119011 hasRelatedWork W2497054225 @default.
- W2056119011 hasRelatedWork W4234719321 @default.
- W2056119011 hasVolume "63" @default.
- W2056119011 isParatext "false" @default.
- W2056119011 isRetracted "false" @default.
- W2056119011 magId "2056119011" @default.
- W2056119011 workType "article" @default.