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- W2056128580 abstract "Matrix isolation spectroscopy has been employed to investigate the molecular structure of the mixed metal fluorides LiNaF2 and CaSrF4. These molecules have been obtained by allowing high-temperature vapour interaction between LiF and NaF or CaF2 and SrF2 species. Vaporization of premixed solid samples has also been carried out. The vapour containing several molecules and among them mixed fluorides has been trapped in Ar matrices maintained at the temperature of ≈ 10 K. The FT IR spectra are interpreted with the aid of polarizable ion model calculations. The mixed fluorides identified in this study are LiNaF2 and CaSrF4. Both have planar ring structures of C2v symmetry. Presence of linear metastable Li2F2 and LiNaF2 molecules is also ascertained." @default.
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- W2056128580 date "1988-08-01" @default.
- W2056128580 modified "2023-10-14" @default.
- W2056128580 title "FT IR study of matrix isolated mixed metal fluorides LiNaF2 and CaSrF4" @default.
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- W2056128580 doi "https://doi.org/10.1016/0301-0104(88)87158-1" @default.
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