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• W2056131844 abstract "Direct capillary zone electrophoretic methods were developed for the separation of the enantiomers of unnatural β-substituted tryptophan analogues such as erythro- and threo-β-methyl-, β-2-propyl-, β-3-pentyl-, β-phenyl- and β-2,5-dimethoxyphenyltryptophan. Cyclodextrins (CDs) were chosen as chiral selectors because of their favorable properties (stability, commercial availability, low cost, UV transparency, inertness, etc.). Capillary zone electrophoresis was carried out using sulfopropylated-α-CD (SP2-α-CD), sulfopropylated-β-CD (SP2-β-CD) both with a degree of substitution of 2 moles/mole cyclodextrin, and sulfopropylated-β-CD (SP4-β-CD) with a degree of substitution of 4 moles/mole β-cyclodextrin. With this technique all compounds investigated are baseline resolved using different background electrolytes and chiral additives. The elution sequence was determined in all cases." @default.
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• W2056131844 date "2009-04-01" @default.
• W2056131844 modified "2023-10-16" @default.
• W2056131844 title "Enantioseparation of β-substituted tryptophan analogues with modified cyclodextrins by capillary zone electrophoresis" @default.
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• W2056131844 doi "https://doi.org/10.1016/j.chroma.2009.01.083" @default.
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