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- W205616463 abstract "A mixed valent vanadium compound NaV 6 O 11 shows a magnetic phase transition at T t =245 K. For the microscopic investigation of the transition at T t , 23 Na-NMR measurements from 70 K to 300 K were carried out on NaV 6 O 11 . The Knight shift, K , and the nuclear spin-lattice relaxation rate, 1/ T 1 , were measured. While 1/ T 1 above T t has an almost constant value, 1/ T 1 below T t shows a gap-type temperature dependence. This is the first direct evidence that the d -electrons at V(1) ions, which form a kagomé lattice in NaV 6 O 11 , exhibit a spin-singlet ground state below T t . The formation of the spin-singlet ground state of V(1) seems to be closely related to the frustration effect." @default.
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- W205616463 date "2001-05-15" @default.
- W205616463 modified "2023-10-14" @default.
- W205616463 title "23Na-NMR Study in NaV6O11" @default.
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- W205616463 doi "https://doi.org/10.1143/jpsj.70.1404" @default.
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