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- W2056166021 abstract "Some mono-aryl substituted 1-methoxycyclopropanols (cyclopropanone hemiacetals) with the following aryl groups, C6H5-, p-CH3C6H4- and p-ClC6H4-, have been prepared in 80-85 % yield by passing ketene at −70°C into a solution of aryldiazomethane in CFCl3 or CCl4, containing an excess of methanol, which adds to the intermediate arylcyclopropanone. It appears that the addition of methanol to the carbonyl group in the arylcyclopropanone takes place preferentially at the least hindered side of the cyclopropyl ring as is shown by structure elucidation (NMR) of the more stable acetates derived from the hemiacetals." @default.
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- W2056166021 date "1975-01-01" @default.
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- W2056166021 title "The chemistry of small ring compounds. Part 29: Synthesis and stereochemistry of some arylcyclopropanone methyl hemiacetals and their acetates" @default.
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- W2056166021 doi "https://doi.org/10.1002/recl.19750940208" @default.
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