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- W2056166688 abstract "The fluorescence lifetime of N,N,N′,N′-tetramethyl- p-phenyIenediamine (TMPD) in the vapor phase has been determined to be 3.2 ± 0.3 ns for excitation at 337 nm. The rate constants for quenching of electronically excited TMPD by ground-state TMPD, O 2 , and CO 2 have been determined to be <1 × 10 −10 cm 3 /s, (9.9 ± 1.0) × 10 −10 cm 3 /s, and <4 × 10 −13 cm 3 /s, respectively. The rate for TMPD implies that self-quenching is negligible up to pressures of at least 10 Torr. The quenching rate by oxygen is sufficiently high to ensure that use of TMPD as a quantitative marker for fuel evaporation in exciplex-based vapor/liquid visualization systems is probably not possible if significant quantities of oxygen—as would be the case in combustion environments—are present." @default.
- W2056166688 created "2016-06-24" @default.
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- W2056166688 date "1989-11-01" @default.
- W2056166688 modified "2023-10-14" @default.
- W2056166688 title "Fluorescence Lifetime and Quenching Rates for N,N,N′,N′-Tetramethyl-P-Phenylenediamine in the Vapor Phase" @default.
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- W2056166688 doi "https://doi.org/10.1366/0003702894204119" @default.
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