Matches in SemOpenAlex for { <https://semopenalex.org/work/W2056168082> ?p ?o ?g. }
Showing items 1 to 69 of
69
with 100 items per page.
- W2056168082 endingPage "4427" @default.
- W2056168082 startingPage "4427" @default.
- W2056168082 abstract "The dissociation constants of 2,4,6-trinitrophenol (picric acid) in a set of ethane-1,2-diol–water mixtures have been determined by the conductometric method at temperatures ranging from –10 to 80 °C. The experimental k values exhibit a regular trend, with a relative maximum in the investigated temperature range for all the binary solvent systems, and they are well fitted by an equation of the type ln K=a0+a1T+a2/T+a3 ln T. In order to verify the reliability of Kmax values, a series of correlations was made, on the basis of the above equation, of Harned's theory and of a pKvs. 1/Iµ plot; all the methods provide results consistent with each other. Furthermore, two empirical equations for the functions K=K(χ) and K=K(T,χ) are proposed in order to try to predict the K values of the studied solute over the whole variation of the investigated T and χ. Both these model equations allow us to extrapolate the K values of picric acid in pure water solution, in which conductometric and potentiometric methods are unable to give consistent values." @default.
- W2056168082 created "2016-06-24" @default.
- W2056168082 creator A5008264110 @default.
- W2056168082 creator A5018007259 @default.
- W2056168082 creator A5021996859 @default.
- W2056168082 creator A5023558972 @default.
- W2056168082 date "1988-01-01" @default.
- W2056168082 modified "2023-09-25" @default.
- W2056168082 title "The ethane-1,2-diol–water solvent system. The dependence of the dissociation constant of picric acid on the temperature and composition of the solvent mixture" @default.
- W2056168082 doi "https://doi.org/10.1039/f19888404427" @default.
- W2056168082 hasPublicationYear "1988" @default.
- W2056168082 type Work @default.
- W2056168082 sameAs 2056168082 @default.
- W2056168082 citedByCount "16" @default.
- W2056168082 countsByYear W20561680822014 @default.
- W2056168082 countsByYear W20561680822016 @default.
- W2056168082 countsByYear W20561680822018 @default.
- W2056168082 countsByYear W20561680822019 @default.
- W2056168082 countsByYear W20561680822023 @default.
- W2056168082 crossrefType "journal-article" @default.
- W2056168082 hasAuthorship W2056168082A5008264110 @default.
- W2056168082 hasAuthorship W2056168082A5018007259 @default.
- W2056168082 hasAuthorship W2056168082A5021996859 @default.
- W2056168082 hasAuthorship W2056168082A5023558972 @default.
- W2056168082 hasConcept C102931765 @default.
- W2056168082 hasConcept C138885662 @default.
- W2056168082 hasConcept C170493617 @default.
- W2056168082 hasConcept C178790620 @default.
- W2056168082 hasConcept C185592680 @default.
- W2056168082 hasConcept C2780471494 @default.
- W2056168082 hasConcept C2781352634 @default.
- W2056168082 hasConcept C40231798 @default.
- W2056168082 hasConcept C41895202 @default.
- W2056168082 hasConcept C55493867 @default.
- W2056168082 hasConcept C74998103 @default.
- W2056168082 hasConcept C75473681 @default.
- W2056168082 hasConceptScore W2056168082C102931765 @default.
- W2056168082 hasConceptScore W2056168082C138885662 @default.
- W2056168082 hasConceptScore W2056168082C170493617 @default.
- W2056168082 hasConceptScore W2056168082C178790620 @default.
- W2056168082 hasConceptScore W2056168082C185592680 @default.
- W2056168082 hasConceptScore W2056168082C2780471494 @default.
- W2056168082 hasConceptScore W2056168082C2781352634 @default.
- W2056168082 hasConceptScore W2056168082C40231798 @default.
- W2056168082 hasConceptScore W2056168082C41895202 @default.
- W2056168082 hasConceptScore W2056168082C55493867 @default.
- W2056168082 hasConceptScore W2056168082C74998103 @default.
- W2056168082 hasConceptScore W2056168082C75473681 @default.
- W2056168082 hasIssue "12" @default.
- W2056168082 hasLocation W20561680821 @default.
- W2056168082 hasOpenAccess W2056168082 @default.
- W2056168082 hasPrimaryLocation W20561680821 @default.
- W2056168082 hasRelatedWork W1582934341 @default.
- W2056168082 hasRelatedWork W1978954532 @default.
- W2056168082 hasRelatedWork W1991482117 @default.
- W2056168082 hasRelatedWork W1996721585 @default.
- W2056168082 hasRelatedWork W2035356582 @default.
- W2056168082 hasRelatedWork W2056168082 @default.
- W2056168082 hasRelatedWork W2107109481 @default.
- W2056168082 hasRelatedWork W2314128555 @default.
- W2056168082 hasRelatedWork W4226156627 @default.
- W2056168082 hasRelatedWork W4790068 @default.
- W2056168082 hasVolume "84" @default.
- W2056168082 isParatext "false" @default.
- W2056168082 isRetracted "false" @default.
- W2056168082 magId "2056168082" @default.
- W2056168082 workType "article" @default.