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- W2056175280 abstract "The hydrogen-atom dipole polarizability α is obtained by a double perturbation expansion based on a Hartree–Fock H0. The expansion α = α0 + λα1 + λ2α2 + ···, where λ is the continuous parameter for the Hartree–Fock perturbing potential, is found to be extremely close to a geometric series with αi+1 / αi = 0.433 ± 0.002. Computation of α as α0[1 − (α1 / α0)]−1 gives 4.499a03 in excellent agreement with the exact value 92a03. The origin of this geometric character is examined and its applicability to some many-electron polarizabilities is demonstrated empirically." @default.
- W2056175280 created "2016-06-24" @default.
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- W2056175280 date "1968-12-01" @default.
- W2056175280 modified "2023-10-02" @default.
- W2056175280 title "Hydrogen-Atom Polarizability as a Hartree–Fock Perturbation Expansion: A Geometric Approximation to Atomic Polarizabilities" @default.
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- W2056175280 doi "https://doi.org/10.1063/1.1669968" @default.
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