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• W2056180252 abstract "Abstract Samples of α,ω-alk oxy-poly (ethylene oxide) with oxyethylene inner blocks of 70 to 150 chain atoms and end blocks ranging from C 1 (methoxy) to C 18 (octadecoxy) have been prepared and characterized. Several experimental methods have been used to investigate their crystalline structure and melting behaviour. The polymers crystallize into stacked structures in which crystalline and non-crystalline layers alternate. The methylene chains are in the non-crystalline layers together with a significant fraction (about 0.2) of the oxyethylene inner block. The crystalline layers contain extended or folded oxyethylene chains, depending upon the relative lengths of the inner and end blocks. The melting points either are roughly independent of methylene block length (extended-chain crystals) or increase with methylene block length (folded-chain crystals). This melting behaviour is explained by a combination of two important effects: conformational restriction of the cilia emerging into the non-crystalline layer and mixing of the methylene and oxyethylene chains in the melt." @default.
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• W2056180252 date "1978-03-01" @default.
• W2056180252 modified "2023-09-27" @default.
• W2056180252 title "Crystallinity and fusion of low molecular weight α, ω-alkoxy-poly(ethylene oxide): methoxy to octadecoxy end-groups" @default.
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• W2056180252 doi "https://doi.org/10.1016/0032-3861(78)90224-0" @default.
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