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- W2056213303 abstract "Imidazolium and 4,5-dihydroimidazolium carbene–CuCl complexes effectively catalyzed the substitution reaction of allylic compounds with Grignard reagents in an SN2′-selective fashion. It was noteworthy that the amount of the imidazolium carbene-CuCl complex could be reduced to 0.001 mol% and the catalysis recorded a high TON (105). Based on the experimental results, the ate-type complex(es) such as [(imidazolium carbene)-CuR2]−(MgX)+ was postulated as an active species." @default.
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- W2056213303 date "2005-12-01" @default.
- W2056213303 modified "2023-10-14" @default.
- W2056213303 title "Allylic substitution reactions with Grignard reagents catalyzed by imidazolium and 4,5-dihydroimidazolium carbene–CuCl complexes" @default.
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- W2056213303 doi "https://doi.org/10.1016/j.jorganchem.2005.07.096" @default.
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