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- W2056216514 abstract "The synthesis of a poly(1,3-dithienylisothianaphthene) (PDTITN) derivative obtained via oxidative polymerization of 5,6-dichloro-1,2-bis(3‘-dodecylthienyl)isothianaphthene is described. PDTITN exhibits a band gap of 1.80−1.85 eV. The redox properties of PDTITN were characterized using cyclic voltammetry and spectroelectrochemisty. Photoexcitation of PDTITN results in photoluminescence (PL) in the near-IR region and the formation of a triplet state. In the presence of a methanofullerene (PCBM) as an electron acceptor, PL and triplet formation of PDTITN are quenched. In photovoltaic devices using blends of the polymer with PCBM, the observed incident-photon-to-collected-electron efficiency (IPCE) up to 24% at 400 nm and the 3 orders of magnitude increase of short circuit current as compared to the polymer alone prove the photoactivity of the PDTITN/PCBM blend in the device." @default.
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- W2056216514 date "2001-10-19" @default.
- W2056216514 modified "2023-10-14" @default.
- W2056216514 title "Synthesis and Characterization of a Poly(1,3-dithienylisothianaphthene) Derivative for Bulk Heterojunction Photovoltaic Cells" @default.
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- W2056216514 doi "https://doi.org/10.1021/jp013073t" @default.
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