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- W2056223353 endingPage "7410" @default.
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- W2056223353 abstract "A catalytic oxidative polycyclization reaction initiated by the carbocyclization of 1,5-dienes with Pd(II) is reported. Trapping of a putative carbocation with suitable functional groups (phenols, alkenes, alcohols, sulfonamide), or rearrangement protocols (Pinacol) yields poly-cyclic products in good yields and in excellent diastereoselectivities. Turnover of the intermediate Pd–C bond is via β-H elimination." @default.
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- W2056223353 date "2004-08-01" @default.
- W2056223353 modified "2023-09-23" @default.
- W2056223353 title "Pd(II)-Catalyzed cyclogeneration of carbocations: subsequent rearrangement and trapping under oxidative conditions" @default.
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- W2056223353 doi "https://doi.org/10.1016/j.tet.2004.06.023" @default.
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